It's a great book, but my personal opinion is that it would have benefited from an editor that recommended some small changes. The previous edition had a TOC which was barely usable because all funny jokes in chapter names like "8 Conditional Manatees". Besides, there were too many jokes embedded in some sections, which made them difficult to follow. I think some of these issues are getting addressed in the current edition.
Nonetheless, the book is very well written and all figures and examples show great attention to detail. I found Gelman et al Regression and Other Stories better for teaching newcomers, and surprisingly insightful. Statistical Rethinking is a good choice for a second course, but perhaps too informal at that stage.