This may currently be a bit beyond foolproof advice for Aunt Tilly [0] to do on her own, but:
1. Get them to use a password manager for their stuff. This can easily be a good idea all on its own, simply so that they don't reuse the same credentials everywhere.
2. The password store can be decrypted with either of two methods: A day-to-day password they memorize, or a longer key which can be stored along with the will. [1]
3. Set up the cloud services to automatically backup and share their encrypted at rest password store from their computer to various relatives and friends.
4. Take the alternate encryption key from step #1, print it on archival paper, seal it inside an opaque tamper-resistant envelope, and store the envelope along with the will--or in such a way that it reaches the right people when the person passes away.
This way they can easily keep things up-to-date with new accounts or password changes, without constantly sending new stuff to a lawyer or safe-deposit box or whatever.
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[0] An archetypal relative who is "not good with computers."
[1] This isn't algorithmically impossible by any means, but it's a use-case not all password managers will support. An alternative is to tell them "never change your master password ever", and then just duplicate it in the sealed envelope.