I have a similar setup, but with AdGuardHome. I used Pi-Hole in the past, but AdGuardHome's UI is from this century at least. That, and the fact that with Pi-Hole it was very difficult have IPv6 working.
I have an instance on my router in my home network for covering all devices by default, and a hosted one to which I connect when outside via mobile network. Split-tunneling with only the DNS routed, so that I don't have to push all traffic through the VPN.